Metal carbonyl complexes M

Reagent and catalyst induced substitution reactions of metal carbonyl complexes. M. O. Albers and N. J. Coville, Coord. Chem. Rev., 1984, 53, 227-259 (153). 

Fig. 4.19 Point groups of octahedral metal carbonyl complexes M(CO)5, M(CO)5X, trawv-M(CO)4X2 and cw-M(CO)4X2. Colour code metal M, green C, grey O, red group X, brown.

Consider a hypothetical metal carbonyl complex M(CO)8 with a square antiprismatic structure (D4d symmetry), A bird s-eye view of this complex is displayed below. Carbonyl groups a to h are labeled in the figure. 

Triphenylcyclopropene was converted into 1-naphthol 137 when it reacted under CO in the presence of Group 6 metal-carbonyl complexes, M(C0) 5 (Scheme 2.92) [147]. A mechanism involving metallacyclobutene and vinylketene complexes was proposed. Catalytic conversion was achieved in the case with Mo(CO)g. 

N.m.r. studies are reported on the triethylphosphine and trisdi-methylaminophosphine complexes with boron halides, and triethylphos-phine complexes with aluminium chloride. A correlation of Sp with the number of phosphorus ligands in metal carbonyl complexes has led to a qualitative rationalization of 8p in terms of a- and 7r-bonding. ... 

Figure 17 Some examples of metal carbonyl complexes with M-Ag bonds.

Salmain, M., Vessieres, A., Butler, I., and Jaouen, G. (1991) N-Succinimidyl (4-pentynoate)hexacarbon yldicobalt A transition-metal carbonyl complex having similar uses to the Bolton-Hunter reagent. Bioconjugate Chem. 2, 13-15. 

Bodner, G.M., May, M.P., and McKinney, L.E., A Fourier transform carbon-13 NMR study of the electronic effects of phosphorus, arsenic, and antimony ligands in transition-metal carbonyl complexes, Inorg. Chem., 19, 1951, 1980. 

Vibrational Spectra of Transition Metal Carbonyl Complexes Linda M. Haines and M. H. Stiddard... 

Low-valent clusters [RM]X are valuable starting reagents for various oxidation reactions as will be shown in the following for the tetrahedral cluster [TMS3CM]4 (M = Ga 383, In 384). (Reactions with metal carbonyl complexes,... 

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