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Metal atoms silyl halides

Allyl silanes will also attack carbonyl compounds when they are activated by coordination of the carbonyl oxygen atom to a Lewis acid. The Lewis acid, usually a metal halide such as TiCLj or ZnCl2, activates the carbonyl compound by forming an oxonium ion with a metal-oxygen bond. The allyl silane attacks in the usual way and the (3-silyl cation is desilylated with the halide ion. Hydrolysis of the metal alkoxide gives a homoallylic alcohol. [Pg.1299]


See other pages where Metal atoms silyl halides is mentioned: [Pg.106]    [Pg.106]    [Pg.1467]    [Pg.5863]    [Pg.589]    [Pg.589]    [Pg.452]    [Pg.1466]    [Pg.5861]    [Pg.5862]    [Pg.178]    [Pg.90]    [Pg.589]    [Pg.569]    [Pg.253]    [Pg.146]    [Pg.147]    [Pg.491]    [Pg.341]    [Pg.2072]    [Pg.314]    [Pg.362]    [Pg.167]    [Pg.318]    [Pg.32]    [Pg.1452]    [Pg.386]    [Pg.162]    [Pg.283]    [Pg.32]    [Pg.317]    [Pg.386]    [Pg.155]    [Pg.2072]    [Pg.265]    [Pg.498]    [Pg.84]    [Pg.13]   
See also in sourсe #XX -- [ Pg.2 , Pg.5 , Pg.8 , Pg.12 , Pg.93 ]




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Atomic halide

Halides metal atoms

Halides silylation

Metal silyl

Metal silyl halides

Silyls metal

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