Medium with multiple components

Medium density can be measured on-line by acoustic methods. An ultrasonic sensor was installed in the autoclave and allowed on-line measuring of the speed of sound in the medium. An example is given in Fig. 5.11 for pure SCCO2. These values are compared with the NIST database and reveal an excellent agreement Knowing the speed of sound and pressure/temperature, it is possible to determine the medium density in the case of single or even multiple components. 

In real situations, there are complex cases such as in biological waste water treatment and fermentation technology (complex media with multiple carbon sources, e.g., molasses, worts, metabolic intermediates, vitamins, etc.) that cannot be treated with the simple model equations fi = fi s) given in Sect. 5.3. In the course of a growth process in a complex medium, the valuable, easily utilized components are exhausted after a short time. For use of the remaining... 

Two models are available for interpreting attenuation spectra as a PSD in suspensions with chemically distinct, dispersed phases using the extended coupled phase theory.68 Both models assume that the attenuation spectrum of a mixture is composed of a superposition of component spectra. In the multiphase model, the PSD is represented as the sum of two log-normal distributions with the same standard deviation, that is, a bimodal distribution. The appearance of multiple solutions is avoided by setting a common standard deviation to the mean size of each distribution. This may be a poor assumption for the PSD (see section 11.3.2). The effective medium model assumes that only one target phase of a multidisperse system needs to be determined, while all other phases contribute to a homogeneous system, the so-called effective medium. Although not complicated by the possibility of multiple solutions, this model requires additional measurements to determine the density, viscosity, and acoustic attenuation of the effective medium. The attenuation spectrum of the effective medium is modeled via a polynomial fit, while the target phase is assumed to have a log-normal PSD.68 This model allows the PSD for mixtures of more than two phases to be determined. 

In molecular property calculations the same mutual interplay of electron correlation, relativity and perturbation operators (e.g. external fields) occurs. For light until medium atoms relativistic contributions were often accounted for by perturbation theory facilitating quasirela-tivistic approximations to the Dirac-Hamiltonian [114-117]. It is well-known that operators like the Breit-Pauli Hamiltonian are plagued by essential singularities and therefore are not to be used in variational procedures. It can therefore be expected that for heavier elements per-turbational inclusion of relativity will eventually become inadequate and that one has to start from a scheme where relativitiy is included from the beginning. Nevertheless very efficient approximations to the Dirac equation in two-component form exist and will be discussed further below in combination with their relevance for EFG calculations. In order to calculate the different contributions to a first-order property as the EFG, Kello and Sadlej devised a multiple perturbation scheme [118] in which a first-order property is expanded as... 

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