Medium-ring-containing biaryls

Spring DR, Krishnan S, Blackwell HE, Schreiber SL, Diversity-oriented synthesis of biaryl-containing medium rings using a one bead/one stock solution platform, J. Am. Chem. Soc., 124 1354-1363, 2002. 

Spring, D.R., Krishnan, S., and. Schreiber, S.L., Towards diversity-oriented, stereoselechve syntheses of biaryl- or bis(aryl)metal-containing medium rings, J. Am. Chem. Soc., 122, 5656, 2000. 

In 2011, Greaney and co-workers used a Cu(OAc)2 oxidant with a Pd(OAc)2 catalyst for an intramolecular CDC reaction that created medium-sized, biaryl-containing rings (Scheme 6.10). ... 

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