Mediator-template

Schalley CA, WeUandt T, Briiggemann J,V6gtle F (2004) Hydrogen-Bond-Mediated Template Synthesis of Rotaxanes, Catenanes, and Knotanes. 248 141-200 Scheer M,see Balazs G (2003) 232 1-23... 

Schalley CA, Weilandt T, Briiggemann J, Vogtle F (2004) Hydrogen-bond-mediated template synthesis of rotaxanes, catenanes, and knotanes. Top Curr Chem 248 141-200... 

Hydrogen-Bond-Mediated Template Synthesis of Rotaxanes, Catenanes, and Knotanes... 

Scheme l Synthesis of a catenate based on a Cu(I)-mediated template effect. The catenane can be liberated by demetallation with cyanide. 

Figure 9. a) The amide-mediated template which was hypothesized to provide access to rotaxane 22. b) A control reaction which was thought not to yield any rotaxane, but led to almost quantitative formation of rotaxane 24. 

Fig. 6.14 (A)[54] TEM images of (a) y-CD-capped gold nanopaiticles tind (b) Cgo-induced aggregation. (c) Schematic illustration of the structure of fullerene-induced network of y-CD-capped gold nanoparticles in aqueous dispersion. (B)[75] (a) Schematic illustration of the mediation-template strategy for quatemeiry ammonium-stabilized gold nanopaiticles and a mediettor (2) (b-d) TEM images of the 2-mediated nanoparticle assemblies prepared by various conditions...

Yamauchi Y, Ohsuna T, Kuroda K. Synthesis and structural characterization of a highly ordered mesoporous Pt-Ru alloy via evaporation-mediated templating . Chem Mater 2007 19 1335-12. 

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