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Mechanism, radical neighboring group effects

Only one example of A, iV-dialkyl diazonium salt was studied, but it provided key information on the mechanism of the solvolysis step in the radical-polar crossover scheme [10]. Thus, the A -allyl substrate 27 was reacted in moist acetone and afforded the primary alcohol 28. Since previous primary substrates, for example la, had afforded tetrathiafulvalenium salts 2a which did not undergo solvolysis, this showed that the A -allyl group was important in exerting a neighboring group effect, assisting the solvolysis of salt 29 via delocalized cation 30. Since ort/m-alkoxy... [Pg.302]

See other pages where Mechanism, radical neighboring group effects is mentioned: [Pg.231]    [Pg.682]    [Pg.386]    [Pg.278]    [Pg.194]    [Pg.46]    [Pg.252]    [Pg.341]    [Pg.215]    [Pg.382]    [Pg.351]    [Pg.573]    [Pg.45]    [Pg.36]    [Pg.520]    [Pg.209]    [Pg.257]    [Pg.9]    [Pg.47]    [Pg.240]   
See also in sourсe #XX -- [ Pg.942 ]



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Mechanism groups

Mechanisms neighboring-group

Neighbor

Neighbor effect

Neighboring group

Neighboring group effects

Radical effective

Radical mechanism

Radicals effects

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