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Matrix-bound transition-metal complexe

Site Isolation Experienced by Matrix-Bound Transition-Metal Complexes... [Pg.424]

Considering this result and proposals of alkane complexes in matrix isolation studies, both before and after Kubas s discovery, Bergman explained results of H-D exchange between the hydride and cyclohexyl group of the complex in Equation 2.20 and kinetic isotope effects for reductive elimination by invoking an intermediate in which the alkane is bound to the transition metal through a C-H bond, This proposal of an alkane complex is now fully accepted, although the precise structure of such a complex in solution is unknown. [Pg.65]

See other pages where Matrix-bound transition-metal complexe is mentioned: [Pg.269]    [Pg.189]    [Pg.192]    [Pg.807]    [Pg.9]    [Pg.428]    [Pg.37]    [Pg.197]    [Pg.98]    [Pg.155]    [Pg.122]    [Pg.311]    [Pg.5847]    [Pg.4]    [Pg.568]    [Pg.5846]    [Pg.80]    [Pg.80]    [Pg.105]    [Pg.1631]    [Pg.102]    [Pg.155]    [Pg.126]    [Pg.294]   
See also in sourсe #XX -- [ Pg.424 , Pg.425 , Pg.426 ]



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Bound complexes

Bounds matrix

Complex matrices

Complexes matrix-bound

Transition matrix

Transition matrix-bound

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