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Mapping binary product

Let us now consider the adjoint operator Td, which in the case of the binary product will be given the special notation T. The operator mapping T - Td - T+, which is then defined through the relations... [Pg.387]

Nitromethane shows the simplest residue curve map with one unstable curved separatrix dividing the triangle in two basic distillation regions. Methanol and acetonitrile give rise two binary azeotropic mixtures and three distillation regions that are bounded by two unstable curved separatrices. Water shows the most complicated residue curve maps, due to the presence of a ternary azeotrope and a miscibility gap with both the n-hexane and the ethyl acetate component. In all four cases, the heteroazeotrope (binary or ternary) has the lowest boiling temperature of the system. As it can be seen in Table 3, all entrainers except water provide the n-hexane-rich phase Zw as distillate product with a purity better than 0.91. Water is not a desirable entrainer because of the existence of ternary azeotrope whose n-hexane-rich phase has a water purity much lower (0.70). Considering in Table 3 the split... [Pg.133]

Sundmacher and Qi (Chapter 5) discuss the role of chemical reaction kinetics on steady-state process behavior. First, they illustrate the importance of reaction kinetics for RD design considering ideal binary reactive mixtures. Then the feasible products of kinetically controlled catalytic distillation processes are analyzed based on residue curve maps. Ideal ternary as well as non-ideal systems are investigated including recent results on reaction systems that exhibit liquid-phase splitting. Recent results on the role of interfadal mass-transfer resistances on the attainable top and bottom products of RD processes are discussed. The third section of this contribution is dedicated to the determination and analysis of chemical reaction rates obtained with heterogeneous catalysts used in RD processes. The use of activity-based rate expressions is recommended for adequate and consistent description of reaction microkinetics. Since particles on the millimeter scale are used as catalysts, internal mass-transport resistances can play an important role in catalytic distillation processes. This is illustrated using the syntheses of the fuel ethers MTBE, TAME, and ETBE as important industrial examples. [Pg.306]

The structures assumed by rapidly P-quenched binary Ti-TM sdloys are mapped in Fig. 5.1. Below a start temperature, the bcc structure begins a spontaneous allotropic transformation by means of a complicated shearing process to a structure known as martensite and designated a or a" depending upon whether the transformation product is hep or orthorhombic. When the distinction between a and a" is unimportant, the martensites are to be herein represented collectively by the notation a " Being of second order, the martensitic transformation is anticipated by a regime of structural fluctuations called difiuse (O phase. As represented in Fig. 5.1, the co phase, as... [Pg.32]

Consider a Turing computable function f(i) that maps the positive integers IN onto a subspace of IN. Then we know from the previous section that there is a quantum Turing machine based on a reversible, classical machine M on which this function can be evaluated. The overall computation of / is described by the unitary operator Uf which is the product of local, unitary transformations Ui. To abbreviate the notation, we will only consider the subspace of the input and output data of the quantum machine. Furthermore, we will write i) to denote a part of the memory in which the number i is stored. For example, using the binary number system,... [Pg.152]


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