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Manganese silyl complexes structures

Oxidative addition of the 16-electron manganese center on the silyl ether leads to silyl-manganese complex III. Attack on III by an incoming alcohol (ROH) leads to complex TV. Pseudorotation gives all four possible structures of IV. Complex IV, having a free proton,... [Pg.89]

Reaction of the Pt complex (13) with (11) gives a silylplatinum complex (14), the silyl group of which has the same configuration as that of (11). The oxidative addition is thus assumed to take place from the front side of the Si—H bond (equation 7). The hydrosilane (11) reacts with a manganese complex (15) to give rise to a complex (16 equation 8), which has a structure similar to the intermediate of the oxidative addition step. °... [Pg.766]

Figure 18. Representation of the structure of silyl-manganese complexes 172. Figure 18. Representation of the structure of silyl-manganese complexes 172.
See other pages where Manganese silyl complexes structures is mentioned: [Pg.235]    [Pg.2069]    [Pg.296]    [Pg.2069]    [Pg.407]    [Pg.125]    [Pg.524]    [Pg.241]    [Pg.2069]    [Pg.171]    [Pg.241]    [Pg.156]    [Pg.236]    [Pg.327]    [Pg.2445]    [Pg.404]   
See also in sourсe #XX -- [ Pg.82 , Pg.86 , Pg.90 ]

See also in sourсe #XX -- [ Pg.82 , Pg.86 , Pg.90 ]



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