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Manganese, density, thermal

Many methods have been used to determine the deuterium eontent of hydrogen gas or water. For H2/D2 mixtures mass speetroseopy and thermal eonduetivity ean be used together with gas ehromatography (alumina aetivated with manganese ehloride at 77 K). For heavy water the deuterium eontent ean be determined by density measurements, refraetive index ehange, or infrared speetroseopy. [Pg.41]

Once the thermal runaway had become established, the high temperature could allow a smelting reaction (reduction of lead oxides by carbon to metallic lead) to occur, and the low m.p. and high density (327°C, 10.6, respectively) would cause the molten lead to concentrate at the base of the reactor, decreasing the lead content and raising the manganese content of the bulk of the clinker residue, as was observed [2],... [Pg.1859]

Several methods have been used to produce different types of OL-1, OMS-1, and OMS-2 materials. The materials that are produced by various methods lead to vastly different materials, that have unique chemical and physical properties. Some of the properties that can be controlled are particle size, color, morphology, average manganese oxidation state, thermal stability, ion-exchange capacity, electrical conductivity, magnetic properties, crystallinity, defect density, desorption of oxygen, and catalytic properties. Table IV summarizes 16 different classes of OMS-1, OMS-2, OL-1, and amorphous manganese oxide (AMO) materials that we have prepared. These materials are separated into different classes because they show different crystalline, chemical and physical properties. For the case of OMS-1 these materials... [Pg.59]

Thermal dissociation in the solid phase takes place if the decomposition point of the product is signihcantly lower than its vaporization point. In the opposite case, thermal dissociation takes place in the gas phase. Halides usually have a significantly lower dissociation temperature than the corresponding oxides that is, dissociation in solid phase is barely possible. The extremely high electron density in a graphite tube at temperatures above 1200°C can lead to a reduction of stable metal oxides of, for instance, iron, chromium, and manganese in solid or liquid phase. This reduction is typically observed at temperatures of around 500°C lower than the dissociation point of the oxides. The last reaction is the dissociation of carbides in the gas phase ... [Pg.211]

When mixtures of Mn(N03)2 and H-ZSM-5 were thermally treated for 2 h at 870 K, XPS revealed a significant decrease in the surface concentration of manganese [35]. Further evidence for introduction of Mn into H-ZSM-5 was provided by the ESR spectra of MnO/H-ZSM-5 and MnCl2/H-ZSM-5 mixtures after heat-treatment at 870 K and 770 K followed by rehydration at ambient temperature [14,35]. The spectra showed a signal with six hyperfine lines typical of Mn + in cation sites with Oj, symmetry. Also, TPDA, TPE and IR (consumption of acidic OH groups, decreased pyridinium ion formation upon pyridine admission to the heat-treated mixture, increased density of... [Pg.61]

Though there are metals other than copper (such as iron, manganese and cobalt) that can accelerate thermal oxidation of polyolefins and related polymers such as EPDM, in practice, however, the inhibition of copper-catalyzed degradation of polyolefins is of paramount importance because of the steadily increasing use of polyolefin insulation over copper conductors. Among polyolefins, polyethylene is still the most common primary insulation material for wire and cable. In the United States, high-density polyethylene and ethylenepropylene copolymers are used in substantial amounts for communications wire insulation. [Pg.114]


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Thermal density

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