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Manganese complexes dioxane

Manganese(lII) carboxylate complexes of nuelearity>5 are limited and are summarized in Table 10. The first hexanuclear complex, [Mn602(02CCMe3)i4] (109), was prepared from Mn(N03)3 and excess pivalic acid in dioxane. This neutral eomplex has an [Mn6(//4-0)2(/U3-02CCMe3)4-(/t-02CCMe3)6] core with both bridging and monodentate pivalates. All manganese centers have a distorted octahedral environment. [Pg.49]

History of the Discovery of the 1,2-Dioxane Synthesis Using Manganese(lll) Complexes... [Pg.40]

Dioxan-3-ol derivatives are formed at ambient temperature during the aerobic oxidation catalyzed by the Mn(II)-Mn(III) redox system. The manganese(III)-enolate complex A would be formed by the reaction of... [Pg.68]

See other pages where Manganese complexes dioxane is mentioned: [Pg.98]    [Pg.1255]    [Pg.1255]    [Pg.88]    [Pg.134]    [Pg.190]    [Pg.800]    [Pg.831]    [Pg.800]    [Pg.134]    [Pg.162]    [Pg.6945]    [Pg.234]    [Pg.44]    [Pg.45]    [Pg.46]    [Pg.68]    [Pg.343]    [Pg.387]   
See also in sourсe #XX -- [ Pg.38 , Pg.47 ]



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Dioxane complexes

Manganese complexes

Manganese complexing

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