Manganese biological concentration

To immobilize a protein the biologic activity of which depends on a cofactor, this cofactor has to be present in sufficient concentration during the immobilization step. Thus, for example, the lectin Concanavalin A is immobilized in the presence of a buffer containing 0.1 M glucose or a-methylmannoside, 1 mM calcium chloride and 1 mM manganese chloride. 

Stable aerosols of fine particulates as well as vapors constitute the greatest health risk because of the likelihood of pulmonary absorption. Correlations between trace element pollution and their concentrations in biological fluids or tissue are not uncommon and have been documented for arsenic (62) and lead (63). Man can absorb 75-85% of inhaled mercury vapor at concentrations of 50-350 pg/M3 (64) and even more at lower concentrations (65). Certain aerosols like vanadium, iron, manganese, and lead may contribute to the formation of secondary atmospheric pollutants (52, 66). 

Daly KL, DiTullio GR (1996) Particulate dimethylsulfoniopropionate removal and dimethylsulfide production by zooplankton in the Southern Ocean. In Kiene RP, Visscher PT, Keller MD, Kirst GO (eds) Biological and environmental chemistry of DMSP and related sulfonium compounds. Plenum Press, New York, pp 223-238 Davidson AT, Marchant HJ (1987) Binding of manganese by Antarctic Phaeocystis pouchetii and the role of bacteria in its release. Marine Biol 95 481-487 DiTullio GR, Smith WO (1995) Relationship Between Dimethylsulfide And Phytoplankton Pigment Concentrations In The Ross Sea, Antarctica. Deep-Sea Res Part 142 873-892... 

Several 3d, 4d, and 5d transition ions were tried, all at fixed pH (6) and fixed concentration withont success. It appears that manganese may be tmly nniqne for biological water splitting. 

Trace metals for which active biological assimilation may be an important factor in controlling surface-water concentrations and distributions include the first-row transition metals iron, zinc, manganese, copper, nickel, and cobalt, along with cadmium. Bruland et al. (1991) compiled data on the composition of plankton in... 

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