Malonic ester, ethoxymagnesium derivative, solution

Malonic ester, ethoxymagnesium derivative, solution of, 30, 70 Malonic ester synthesis, 30, 7... [Pg.56]

ETHYL BUTYL ESTER, 37, 34 METHYLENE-, DIETHYL ESTER, 38, 22 Malonic ester, acylation by o-nitro-benzoyl chloride, 30, 70 ethoxymagnesium derivative, solution of, 30, 70 37, 20 Malonic ester syntheses, 30, 7 Malononitrile, 37, S3 Malonyl dichloride, 33, 20 Mandelic acid, 36, 3 -bromo-, 35, 11... [Pg.56]

A general convenient alkyl methyl ketone synthesis, which utilises the /7-keto ester system as an intermediate, involves the acylation of a malonate ester by way of the ethoxymagnesium derivative. Hydrolysis and decarboxylation to the ketone is accomplished by heating in acid solution the synthesis of cyclohexyl methyl ketone is the illustrative example (Expt 5.96). [Pg.619]

See also in sourсe #XX -- [ Pg.30 , Pg.70 ]

See also in sourсe #XX -- [ Pg.30 , Pg.70 ]

See also in sourсe #XX -- [ Pg.30 , Pg.70 ]

See also in sourсe #XX -- [ Pg.30 , Pg.70 ]

See also in sourсe #XX -- [ Pg.30 , Pg.70 ]

See also in sourсe #XX -- [ Pg.30 , Pg.70 ]

See also in sourсe #XX -- [ Pg.30 , Pg.70 ]

See also in sourсe #XX -- [ Pg.30 , Pg.70 ]

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