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Magnetization in Hartree-Fock free-electron gas

From these definitions, and from the fact that AT = A t + A i, we find [Pg.249]

Notice that in the simple approximation we are considering, the free-electron gas, there are no other terms involved in the total energy since we neglect the Coulomb interactions and there is no exchange interaction between spin-up and spin-down electrons. [Pg.249]

We recall the defiiution of the average volume per particle through the variable rs, the radius of the sphere that encloses this average volume  [Pg.249]

While the above discussion is instructive on how exchange interactions alone can lead to non-zero magnetization, this simple model is not adequate to describe reah-stic systems. There are several reasons for this, having to do with the limitations of both the Hartree-Fock approximation and the uniform electron gas approximation. First, the Hartree-Fock approximation is not realistic because of screening and [Pg.250]


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