Magnetic susceptibility contributions

In the case of magnetically coupled systems. Curie relaxation is simply additive as long as the magnetic susceptibility is the sum of the two components. When the magnetic susceptibility is not a simple sum of the components, the magnetic susceptibility contribution of each metal ion should be evaluated. 

This equation gives the sum of the magnetic susceptibility contributions of... 

The disappearance of the paramagnetism of palladium-silver alloys (rich in Pd) when the ratio (H + Ag)/Pd = 0.6 (24) illustrates that the effect of both these alloying" elements in palladium is additive and each one contributes essentially in the same way to the change of magnetic susceptibility of palladium. 

Fig. 7 Temperature dependence of the static magnetic susceptibility of (a) (EDT-TTFBr2)2 FeBr4 (b) (EDO-TTFBr2)2FeCl4 (c) (EDO-TTFBr2)2FeBr4 measured at an external field of B = 1 T after the core diamagnetic contributions are subtracted...

The magnetic susceptibility of p-[Fe(Cp )2][Pt(mnt)2] follow a Curie-Weiss behavior with 6 - 9.8 K. The dominant ferromagnetic interactions are assigned to the magnetic intrachain D+A interactions from the type I chains, as the contribution from the D+ [ A2]2 D+ unit chains is expected to respect only to the cations due to the strong dimerization of the anions, S - 0 for [A2]2. ... 

These dimeric complexes involve, in their neutral state, two metal atoms in the (III) oxidation state. In the vanadium complexes such as [CpV(bdt)]2 and [CpV(tft)]2, the V—V bond length, 2.54 A in [CpV(bdt)]2, are shorter than observed in model complexes with a single V—V bond, indicating a partial double-bond character, also confirmed by a measured magnetic moment of 0.6 fiB in [CpV(tfd)]2, lower than expected if the two remaining unpaired electrons contribute to the magnetic susceptibility [20, 49]. This class of complexes most probably deserves deeper attention in order to understand their exact electronic structure. 

The temperature dependence of the molar magnetic susceptibility (x) of an assembly of paramagnetic spins without interaction is characterized by the Curie behavior with x = C/T where C = /Vy2( 2.S (.S + l)/3k. It is a very common situation in the organometallic chemistry of radical species when the spin density is essentially localized on the metal atom. Since, in most cases, this atom is surrounded by various innocent ligands, intermolecular interactions are very weak and in most cases are reflected by a small contribution described by a Curie-Weiss behavior, with x = C/(T 0) where 0 is the Curie-Weiss temperature. A positive value for 0 reflects ferromagnetic interactions while a negative value — the most common situation — reflects an antiferromagnetic interaction. 

The atomic properties satisfy the necessary physical requirement of paralleling the transferability of their charge distributions - atoms that look the same in two molecules contribute identical amounts to all properties in both molecules, including field-induced properties. Thus the atoms of theory recover the experimentally measurable contributions to the volume, heats of formation, electric polarizability, and magnetic susceptibility in those cases where the group contributions are found to be transferable, as well as additive additive [4], The additivity of the atomic properties coupled with the observation that their transferability parallels the transferability of the atom s physical form are unique to QTAIM and are essential for a theory of atoms in molecules that purports to explain the observations of experimental chemistry. 

H202 can be a potential source of many radicals (e.g., OH, 02H, etc.). However, EPR spectroscopy did not reveal the presence of any of these radicals, indicating that their concentrations are not very significant. They may be highly unstable. Thus, their contribution to the total magnetic susceptibility is apparently negligible. 

Beside fat, the content and distribution of connective tissue in the meat is also considered to be of importance as these contribute to meat toughness. Based on differences in magnetic susceptibility compared with the surrounding muscle tissue, Bonny et al 23 succeeded in visualizing the distribution of connective tissue in beef muscles. Clear differences in the organisation of connective tissue were demonstrated between two different muscle types. 

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