Magnetic, para

In conclusion, it appears that only a relatively small number of spin-labelled moieties can be introduced into the polyacetylene skeleton through modification reactions. the magnetic (para, ferro) properties of the modified polyacetylenes were therefore very poor, but in all cases there was an interaction between the localized moments of spin labels and the conduction electrons (holes) in iodine-doped, modified polyacetylene [39]. New routes for obtaining ferromagnetic and antiferromagnetic materials from verdazyl radicals have since been developed [39a]. 

The magnetic regulators allow to synthesize in one module of the X-ray apparatus main cir-euit commutator, form converter, noncontact smooth ac voltage amplitude regulator, para-metrie stabilizer, ac supply filter, fimetional protection against the short-circuit in the X-ray tube and protection against emergencies in the control circuits. 

Here we shall consider two simple cases one in which the order parameter is a non-conserved scalar variable and another in which it is a conserved scalar variable. The latter is exemplified by the binary mixture phase separation, and is treated here at much greater length. The fonner occurs in a variety of examples, including some order-disorder transitions and antrferromagnets. The example of the para-ferro transition is one in which the magnetization is a conserved quantity in the absence of an external magnetic field, but becomes non-conserved in its presence. 

As in the case of hydrogen and tritium, deuterium exhibits nuclear spin isomerism (see Magnetic spin resonance) (14). However, the spin of the deuteron [12597-73-8] is 1 instead of S as in the case of hydrogen and tritium. As a consequence, and in contrast to hydrogen, the ortho form of deuterium is more stable than the para form at low temperatures, and at normal temperatures the ratio of ortho- to para-deuterium is 2 1 in contrast to the 3 1 ratio for hydrogen. 

Proton magnetic resonance (carbon tetrachloride) S 3.75 (singlet with fine structure) infrared (neat) cm. 2985, 2273, 1667, 1527, 1515 fluorine magnetic resonance (carbon tetrachloride) p.p.m. (CFCI3 internal standard) 142.4 (symmetrical multiplet, 2 ortho F), 153.8 (triplet with flne structure, 1 para P, J = 20 Hz), 161.7 (multiplet, 2 meta F). 

The spectral properties of pentafluorophenylcopper te-tramer are as follows infrared (Nujol) cm. 1630 medium 1391 medium 1353 medium 1275 medium 1090,1081, and 1071 strong triplet 978 strong 785 medium fluorine magnetic resonance (tetrahydrofuran with trichlorofluoromethane as internal reference) 8 (multiplicity, number of fluorines, assignment, coupling constant J in Hz.) 107.2 (20-line multiple , 2, ortho F), 153.4 (triplet of triplets, 1, para F, J= 1.3 and 20), 162.3 (17-line multiplet, 2, meta F). Absorptions at 820-900, 1100-1125, and 1290 cm.- in the infrared spectrum and at 8 3.05 in the proton magnetic resonance spectrum indicate that dioxane is still present. 

This magnetic behavior is very sensitive to the chemical structure of the spin carrier and to the crystal packing. For instance, for the para-nitro substituted derivative, Nit(p-NO )Ph, which crystallizes in four different phases, the p phase only orders ferromagnetically (Tc = 0.6 K) [8,9], Moreover, attaching the nitro group in the meta-, rather than the / ara-position of the phenyl, leads to an antiferromagnetic compound [2],... 

In terms of chemical equivalence, (or more accurately, chemical shift equivalence) clearly, Ha is equivalent to Ha. But it is not magnetically equivalent to Ha because if it was, then the coupling between Ha and Hb would be the same as the coupling between Ha and Hb. Clearly, this cannot be the case since Ha is ortho to Hb but Ha is para to it. Such spin systems are referred to as AA BB systems (pronounced A-A dashed B-B dashed). The dashes are used to denote magnetic non-equivalence of the otherwise chemically equivalent protons. What this means in practise is that molecules of this type display a highly characteristic splitting pattern which would be described as a pair of doublets with a number of minor extra lines and some broadening at the base of the peaks (Spectrum 5.6). 

Figure 12.2 Magnetic field dependence of the energy levels of ortho- and para-H2. Parahydrogen (p-H2) is a singlet that is unaffected by the magnetic field, whereas orthohydrogen (o-H2) is a triplet. Its energy levels split, showing the Zeeman effect.

Other Examination. All circumferential butt and miter groove welds shall be examined by 100% radiography in accordance with para. IP-10.5.2. Alternatively, when specified by the engineering design, ultrasonic examination 100% shall be performed in accordance with para. IP-10.5.5. Socket welds and branch connection welds that are not radiographed shall be examined by magnetic particle or liquid penetrant methods in accordance with para. IP-10.5.4 or IP-10.5.3. 

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