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Magnetic fields paramagnetic contribution

The equivalent of the spin-other-orbit operator in eq. (8.30) splits into two contributions, one involving the interaction of the electron spin with the magnetic field generated by the movement of the nuclei, and one describing the interaction of the nuclear spin with the magnetic field generated by the movement of the electrons. Only the latter survives in the Born-Oppenheimer approximation, and is normally called the Paramagnetic Spin-Orbit (PSO) operator. The operator is the one-electron part of... [Pg.212]

Chemical shifts, as treated by Ramsey (113), are comprised of separate diamagnetic and paramagnetic contributions. The diamagnetic term was considered to arise from the response of the extranuclear electrons to the external magnetic field and had been given earlier by Lamb (65) as... [Pg.234]

See other pages where Magnetic fields paramagnetic contribution is mentioned: [Pg.114]    [Pg.224]    [Pg.448]    [Pg.1446]    [Pg.171]    [Pg.114]    [Pg.125]    [Pg.73]    [Pg.250]    [Pg.200]    [Pg.197]    [Pg.209]    [Pg.210]    [Pg.35]    [Pg.113]    [Pg.241]    [Pg.843]    [Pg.181]    [Pg.597]    [Pg.253]    [Pg.127]    [Pg.67]    [Pg.2]    [Pg.238]    [Pg.239]    [Pg.28]    [Pg.107]    [Pg.13]    [Pg.173]    [Pg.163]    [Pg.106]    [Pg.138]    [Pg.189]    [Pg.192]    [Pg.200]    [Pg.273]    [Pg.296]    [Pg.208]    [Pg.74]    [Pg.142]    [Pg.330]    [Pg.330]    [Pg.86]    [Pg.119]    [Pg.82]    [Pg.235]    [Pg.29]    [Pg.75]    [Pg.171]   
See also in sourсe #XX -- [ Pg.335 ]



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