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Magnetic field effects pattern

Several chapters of this book show how magnetic field effects, as well as CIDEP and CIDNP spectral patterns, can be used to solve chemical problems. It should be noted that the study of how applied magnetic fields perturb chemical reactivity is a topic that is highly relevant to biological processes involving radical pairs, for example, photosynthesis. ... [Pg.5]

ESEEM is a pulsed EPR technique which is complementary to both conventional EPR and ENDOR spectroscopy(74.75). In the ESEEM experiment, one selects a field (effective g value) in the EPR spectrum and through a sequence of microwave pulses generates a spin echo whose intensity is monitored as a function of the delay time between the pulses. This resulting echo envelope decay pattern is amplitude modulated due to the magnetic interaction of nuclear spins that are coupled to the electron spin. Cosine Fourier transformation of this envelope yields an ENDOR-like spectrum from which nuclear hyperfine and quadrupole splittings can be determined. [Pg.385]


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See also in sourсe #XX -- [ Pg.316 , Pg.317 , Pg.318 , Pg.325 , Pg.326 ]




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