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Macrocyclic ligands conjugation

The formation of the macrocyclic complex (98) is a template reaction reminiscent of phthalocyanine synthesis, and aza linkages are formed (Scheme 56).242 The resulting complex (98) can be transformed into a complex with a fully conjugated macrocyclic ligand. The dibromocobaIt(III) complex related to (98) can also be prepared and can function to some extent as a model for vitamin... [Pg.194]

Macrocyclic ligands are usually quite selective with regard to the ionic radius of the metal ion they will bind (those that are bound preferentially are those that fit the cavity). Tetrapyrroles are especially selective in this regard because of their rigidity, which arises from the conjugated network of double bonds. [Pg.96]

NONTEMPLATE SYNTHESES OF COMPLEXES WITH CONJUGATED MACROCYCLIC LIGANDS... [Pg.44]

Nontemplate Syntheses of Complexes with Conjugated Macrocyclic Ligands 45... [Pg.45]

METAL ION-CONTROLLED SYNTHESIS AND RING CONTRACTION OF A CONJUGATED, PLANAR, HEXADENTATE, MACROCYCLIC LIGAND... [Pg.173]

See other pages where Macrocyclic ligands conjugation is mentioned: [Pg.907]    [Pg.10]    [Pg.186]    [Pg.41]    [Pg.132]    [Pg.39]    [Pg.257]    [Pg.297]    [Pg.183]    [Pg.193]    [Pg.432]    [Pg.259]    [Pg.1257]    [Pg.655]    [Pg.98]    [Pg.108]    [Pg.358]    [Pg.364]    [Pg.1590]    [Pg.183]    [Pg.526]    [Pg.225]    [Pg.907]    [Pg.62]    [Pg.141]    [Pg.784]    [Pg.97]    [Pg.259]    [Pg.1257]    [Pg.40]    [Pg.379]    [Pg.379]    [Pg.380]    [Pg.382]    [Pg.132]    [Pg.943]    [Pg.3713]   
See also in sourсe #XX -- [ Pg.10 ]



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Ligand conjugation

Macrocycles Macrocyclic ligands

Macrocycles conjugated

Macrocyclic ligands conjugated

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