M, electron mass

Let us start with the kinetic energy, T = mv2/2 = p2/2m, where p = momentum = mv (m = electron mass, v = velocity). In its exact form, Heisenberg s Principle states that (Born, 1969) ... 

Another property that is related to chemical hardness is polarizability (Pearson, 1997). Polarizability, a, has the dimensions of volume polarizability (Brinck, Murray, and Politzer, 1993). It requires that an electron be excited from the valence to the conduction band (i.e., across the band gap) in order to change the symmetry of the wave function(s) from spherical to uniaxial. An approximate expression for the polarizability is a = p (N/A2) where p is a constant, N is the number of participating electrons, and A is the excitation gap (Atkins, 1983). The constant, p = (qh)/(2n 2m) with q = electron charge, m = electron mass, and h = Planck s constant. Then, if N = 1, (1/a) is proportional to A2, and elastic shear stiffness is proportional to (1/a). 

Materials and substances are composed of particles such as molecules, atoms and ions, which in turn consist of much smaller particles of electrons, positrons and neutrons. In electrochemistry, we deal primarily with charged particles of ions and electrons in addition to neutral particles. The sizes and masses of ions are the same as those of atoms for relatively light lithiiun ions the radius is 6 x 10 m and the mass is 1.1 x 10" kg. In contrast, electrons are much smaller and much lighter them ions, being 1/1,000 to 1/10,000 times smaller (classical electron radius=2.8 x 10 m, electron mass = 9.1 x 10" kg). Due to the extremely small size and mass of electrons, the quantization of electrons is more pronoimced than that of ions. Note that the electric charge carried by an electron (e = -1.602 X 10 C) is conventionally used to define the elemental unit of electric charge. 

Eq. 1. h Planck s constant e dielectric constant m, electron mass m hole effective mass this is indeed the case for isolated silicon particles [11] as well as for compact films of nc-Si (25]... 

Last sentence on page 249 should read m. = electronic mass instead of m = electronic mass. 

A = symmetry group designation G = reciprocal lattice vector I = intensity k = crystal momentum m = electron mass p = dipole moment A.E = energy spread. 

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