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Lower critical solution temperature Monodisperse

The critical point (Ij of the two-phase region encountered at reduced temperatures is called an upper critical solution temperature (UCST), and that of the two-phase region found at elevated temperatures is called, perversely, a lower critical solution temperature (LCST). Figure 2 is drawn assuming that the polymer in solution is monodisperse. However, if the polymer in solution is polydisperse, generally similar, but more vaguely defined, regions of phase separation occur. These are known as "cloud-point" curves. The term "cloud point" results from the visual observation of phase separation - a cloudiness in the mixture. [Pg.183]

The cloud point is close to, but not necessarily equal to the lower consolute solution temperature for polydisperse nonionic surfactants (97). These are equal if the surfactant is monodisperse. Since the lower consolute solution temperature is like a critical point for liquid—liquid mixtures, the dilute and coacervate phases have the same composition, and the volume fraction of solution which the coacervate comprises is a maximum at this temperature (98). If a coacervate phase containing a high concentration of surfactant is desired, the solution should be at a temperature well above the cloud point. [Pg.23]


See other pages where Lower critical solution temperature Monodisperse is mentioned: [Pg.619]    [Pg.781]    [Pg.339]    [Pg.6247]    [Pg.8398]    [Pg.301]    [Pg.462]    [Pg.281]    [Pg.302]   
See also in sourсe #XX -- [ Pg.68 , Pg.70 ]




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