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Long-range and through space

Long-range coupling through space can occur by the direct interaction of nuclear magnetic dipoles of molecules with one another. In liquids this is averaged to zero because of the rapid molecular motions. In solids, however, molecules have a fixed orientation with respect to one another and one can therefore observe dipolar coupling. [Pg.85]

M. N. Paddon-Row, K. D. Jordan, Through-Bond and Through-Space Interactions in Unsaturated Hydrocarbons Their Implications for Chemical Reactivity and Long-Range Electron Transfer , in J. F. Liebman, A Greenberg (Eds.) Modem Models of Bonding and Delocalization, Vol. 6, VCH Publishers, New York 1988, pp. 115-194. [Pg.290]

It should be noted that the existence of methods based on both dipolar and J couplings opens up the possibihty for distinguishing through-bond connectivities and through-space proximities on a medium- to long-range, such that insight into in-... [Pg.308]

See other pages where Long-range and through space is mentioned: [Pg.1065]    [Pg.1067]    [Pg.1065]    [Pg.1067]    [Pg.1065]    [Pg.1067]    [Pg.1065]    [Pg.1067]    [Pg.1065]    [Pg.1067]    [Pg.1065]    [Pg.1067]    [Pg.207]    [Pg.122]    [Pg.380]    [Pg.344]    [Pg.104]    [Pg.344]    [Pg.1005]    [Pg.82]    [Pg.439]    [Pg.1004]    [Pg.214]    [Pg.78]    [Pg.114]    [Pg.295]    [Pg.312]    [Pg.313]    [Pg.221]    [Pg.182]    [Pg.104]    [Pg.260]    [Pg.267]    [Pg.127]    [Pg.151]    [Pg.152]    [Pg.218]    [Pg.58]    [Pg.134]    [Pg.28]    [Pg.90]    [Pg.340]    [Pg.268]    [Pg.268]    [Pg.11]    [Pg.113]    [Pg.254]    [Pg.265]   
See also in sourсe #XX -- [ Pg.1067 , Pg.1068 ]

See also in sourсe #XX -- [ Pg.1067 , Pg.1068 ]

See also in sourсe #XX -- [ Pg.1067 , Pg.1068 ]



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