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Loline biosynthesis

The biosynthesis of the lolines has been almost completely elucidated though a few questions remain. The pathway is diverging from the one leading to normal pyrrolizidine alkaloids (see Sect. 3.7). A decisive intermediate is represented by the... [Pg.267]

There are no reported studies of loline alkaloid biosynthesis. Loline has been thought to arise via spermidine and retronecine (1) (21) however, this pathway would require loss of a carbon, possibly via a Curtlus type rearrangement, to form the norpyrrolizidine system found in loline-type alkaloids. There is no literature precedent for such a rearrangement in alkaloid... [Pg.332]

See other pages where Loline biosynthesis is mentioned: [Pg.561]    [Pg.308]    [Pg.334]    [Pg.561]    [Pg.308]    [Pg.334]    [Pg.418]    [Pg.419]    [Pg.307]    [Pg.413]    [Pg.421]    [Pg.292]    [Pg.690]    [Pg.179]    [Pg.267]    [Pg.270]    [Pg.752]    [Pg.320]    [Pg.331]   
See also in sourсe #XX -- [ Pg.561 ]



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