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Lithium amide/alkyllithium interactions

Dynamics of the Lithium Amide/Alkyllithium Interactions Mixed Dimers and Beyond... [Pg.43]

The presence of the phenyl ring is not essential for the carbometallation to proceed. For example, treatment of diallylamines, or related systems, with alkyllithium reagents leads to several trianionic intermediates [87] (Scheme 7-74). The interaction of the lithium atom of the amide with the alkyl group of the organolithium reagent together with the simultaneous proximity effect allows the coordination of the double bond to the lithium atom and consequently the addition reaction occurs. [Pg.166]

See other pages where Lithium amide/alkyllithium interactions is mentioned: [Pg.213]    [Pg.213]    [Pg.44]    [Pg.314]    [Pg.49]    [Pg.57]   
See also in sourсe #XX -- [ Pg.43 ]



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