Liquid comprehensive bibliography

Comprehensive bibliography for liquid-liquid equilibrium data. 

If the solid is first equilibrated with saturated vapor, then immersed in pure liquid adsorbate, the solid-vapor interface is destroyed and the heat liberated should correspond to /,. die surface energy of the pure liquid. The above assumption is made in what is termed the absolute method of Harkins and Jura (HJa) [107] who obtained a heat of immersion of 1.705 kJ kg-1 for titanium dioxide which, when divided by the surface energy of the adsorbent, water (11.8 kJ kg-1) gave a surface area of 14.4 m2 g-1 in agreement with the BET value. For a comprehensive bibliography and description of the calorimeter used, readers are referred to Adamson [30]. The validity of the HJa method may be questioned because exposure to a saturating vapor causes capillary condensation which reduces the available surface. A correction is also required for the thickness of the adsorbed film. 

The reader is recommended to consult the relevant textbooks56 (see also Bibliography, Section 9.10) for a more comprehensive account of chemical derivatisation in liquid chromatography. 

Before discussing the role of surfactants and their chemical structure in the preparation and stabUization of emulsions, it is important to have in mind a clear concept of the physical and theoretical aspects of liquid-liquid interfaces and the stabilization mechanisms available. Detailed discussions of these topics can be found in the works cited in the Bibliography. What follows is only a brief summary of some current thinking on the subject no attempt is made to provide a comprehensive overview. 

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