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Trimers linewidths

In Reference 4, this "alternating linewidth" effect (8) was shown to be consistent with a temperature dependent pseudorotation in Kj. A correlation diagram, which relates transition fields for the three obtuse angled trimer geometries, qualitatively predicts line broadening for M = + and h when pseudorota-... [Pg.75]

Figures 3a and 3b show, respectively, observed and simulated spectra for the pseudorotating trimer at T = 4.2 K. Absorption linewidths for the "bar spectrum" were derived from Equation (10),... Figures 3a and 3b show, respectively, observed and simulated spectra for the pseudorotating trimer at T = 4.2 K. Absorption linewidths for the "bar spectrum" were derived from Equation (10),...
Trimer linewidths were compared with both an exponential, Xj,... [Pg.78]

Figure 5. Comparison of measured ESR linewidths (V) with assumed temperature dependence in trimer correlation times (tJ a, tc — uT b, tc —... Figure 5. Comparison of measured ESR linewidths (V) with assumed temperature dependence in trimer correlation times (tJ a, tc — uT b, tc —...
Silicate solutions consist of many forms Q°-monomer (A) Q -dimer (B) or other end groups Q -cyz]k, trimer (C) Q -middle groups (D) of chain or cyclic silicate anions gj-prismatic hexamers (E). The intensities ( concentration)) and linewidths (rate of... [Pg.29]

See other pages where Trimers linewidths is mentioned: [Pg.256]    [Pg.357]    [Pg.623]    [Pg.70]    [Pg.72]    [Pg.75]    [Pg.75]    [Pg.75]    [Pg.77]    [Pg.78]    [Pg.78]    [Pg.80]    [Pg.125]    [Pg.134]    [Pg.274]    [Pg.200]    [Pg.30]    [Pg.51]   
See also in sourсe #XX -- [ Pg.75 ]



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