Lineshape intermediate exchange regime

In this chapter, we discuss NMR methods for rate measurements in all three regimes. First we discuss a new way of looking at the coalescing lineshapes in intermediate exchange. Then we cover standard and alternative NMR methods for studies of slow and fast chemical exchange. For many... 

For the intermediate exchange where the resonances change upon passing from a slow into a fast regime, the lineshape can be described by McConnell s modification of the Bloch equations [17], For a first-order two-site exchange without homonuclear scalar coupling, for example, the lineshape is given by ... 

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