Ligand field spectra Tanabe-Sugano diagram

Fig. 10 Contributions to L-edge spectral shape (a) Ligand field and electron configuration of low-spin Fe(III). (b) The two transitions with a ratio of 1 4 that would be obtained in the absence of spin-orbit coupling and electron repulsion, (c) The five states that arrive from the addition of e -e repulsion, (d) d6 Tanabe-Sugano diagram with the transitions indicated on the strong field (right) side, (e) Spectrum simulated with the effects of the metal p core hole (both spin-orbit and repulsion), (f) Adds 3d spin-orbit coupling, (g) Shows the o and 7t density of states distributed across the final state spectrum...

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