Ligand cyclopentadienyl dithiocarbamate

Electrochemical recognition, 39 80 anions, macrocyclic and acyclic polycobalti-cinium ligand systems, 39 134-140 cations, 39 81-133 ammonium cation, 39 128-133 crown ether and bis crow ether ligands containing bipyridyl transition metal recognition sites, 39 111 crown ether dithiocarbamate and dithi-olene complexes, 39 123-124 di-h-cyclopentadienyl-molybdenum(IV) and -tungsten(IV) crown ether complexes, 39 107-108... 

A cyclometallated azobenzene eomplex 91 was identified as a new class of highly efficient photorefractive materials.Gyclopalladated azobenzenes with N,0 chelating ligands and cyclic voltammetric studies were reported.Mesomorphic materials exhibiting a nematic phase were derived from a cyclopalladated azo compound.Mesogenic cyclopentadienyl cyclopalladated azobenzene eomplexes were also made. " Reactions of cyclopalladated azobenzenes were studied with xanthates and dithiocarbamates yielding ternary complexes. " The products were studied electroehemically. 

Dithiocarbamates (R2CNSP are a versatile class of monoanionic 1,1-dithio ligands (Fig. 1) and as they are easily prepared, a wide range of chemistry has been developed around them. Indeed, they rank alongside such ligands as phosphines and cyclopentadienyls in their versatility and abundance. ... 

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