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Ligand binding early studies

Because of the relatively poor coordinating properties displayed by the P-menthyl-substituted monodentate ligands toward some catalytically useful metals like rhodium and iridium, development of the coordination chemistry of chelating phosphetanes was required. Early studies established that the bidentate ligand P(6 ),C (6 )-43 binds well to rhodium centers. It gives the chelating complex 26 with [Rh(COD)2]PF6 and the bimetallic compound 68 when reacted with [Rh(COD)Cl]2 under an atmosphere of CO (COD = cyclooctadiene Scheme 5) <19950M4983>. [Pg.492]

See other pages where Ligand binding early studies is mentioned: [Pg.444]    [Pg.509]    [Pg.427]    [Pg.535]    [Pg.266]    [Pg.719]    [Pg.192]    [Pg.273]    [Pg.242]    [Pg.85]    [Pg.136]    [Pg.712]    [Pg.415]    [Pg.294]    [Pg.327]    [Pg.123]    [Pg.153]    [Pg.69]    [Pg.293]    [Pg.115]    [Pg.331]    [Pg.376]    [Pg.502]    [Pg.89]    [Pg.52]    [Pg.169]    [Pg.3]    [Pg.394]    [Pg.758]    [Pg.761]    [Pg.474]    [Pg.614]    [Pg.18]    [Pg.1956]    [Pg.5]    [Pg.109]    [Pg.644]    [Pg.352]    [Pg.366]    [Pg.339]    [Pg.156]    [Pg.176]    [Pg.50]    [Pg.415]    [Pg.98]    [Pg.141]    [Pg.232]    [Pg.59]    [Pg.690]   
See also in sourсe #XX -- [ Pg.376 , Pg.377 , Pg.378 , Pg.379 ]



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