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Lead tetraacetate oxidations overoxidation

The structures of the disaccharides and higher saccharides (obtained by partial hydrolysis of polysaccharides) can be examined by periodate or lead tetraacetate oxidation. Ahlborg studied the periodate oxidation of disaccharides and starch dextrins in 0.5 N sulfuric acid. Since the intermediate formate esters were hydrolyzed, these conditions were favorable for overoxidation. The (1 — 4)- and (1 —> 6)-linkages in the starch dextrins were each found to be associated with a characteristic consumption of oxidant. Neumtiller and Vasseur studied periodate oxidation in solutions of various acidities, from strongly acid to neutral, and showed that there were differences between different types of disaccharides. [Pg.77]

See other pages where Lead tetraacetate oxidations overoxidation is mentioned: [Pg.55]    [Pg.77]    [Pg.211]    [Pg.46]    [Pg.54]    [Pg.81]    [Pg.154]    [Pg.195]    [Pg.197]    [Pg.200]    [Pg.213]   
See also in sourсe #XX -- [ Pg.189 , Pg.190 , Pg.191 ]



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Lead oxidation

Lead tetraacetate

Lead tetraacetate oxidation

Lead tetraacetate oxidative

Overoxidation

Overoxidization

Oxidants lead tetraacetate

Tetraacetate

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