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Langevin equation constrained Brownian motion

Constraints may be introduced either into the classical mechanical equations of motion (i.e., Newton s or Hamilton s equations, or the corresponding inertial Langevin equations), which attempt to resolve the ballistic motion observed over short time scales, or into a theory of Brownian motion, which describes only the diffusive motion observed over longer time scales. We focus here on the latter case, in which constraints are introduced directly into the theory of Brownian motion, as described by either a diffusion equation or an inertialess stochastic differential equation. Although the analysis given here is phrased in quite general terms, it is motivated primarily by the use of constrained mechanical models to describe the dynamics of polymers in solution, for which the slowest internal motions are accurately described by a purely diffusive dynamical model. [Pg.67]


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