Laminar flow kinetics

Similar kinetics have been observed for some [91] but not all [116] animal/insect lines. Trials conducted over a range of average shear stresses (Fig. 2) clearly indicate a higher degree of suspension sensitivity to turbulent, rather than laminar, flow conditions. Similar effects have been reported by other workers for plant [57] and mammalian [86,114,122] systems. From these... 

Micro reactors permit high-throughput screening of process chemistries imder controlled conditions, unlike most conventional macroscopic systems [2], In addition, extraction of kinetic parameters from sensor data is possible, as heat and mass transfer can be fully characterized due to the laminar-flow condihons applied. More uniform thermal condihons can also be utilized. Further, reactor designs can be developed in this way that have specific research and development funchons. 

The basic theory of mass transfer to a RHSE is similar to that of a RDE. In laminar flow, the limiting current densities on both electrodes are proportional to the square-root of rotational speed they differ only in the numerical values of a proportional constant in the mass transfer equations. Thus, the methods of application of a RHSE for electrochemical studies are identical to those of the RDE. The basic procedure involves a potential sweep measurement to determine a series of current density vs. electrode potential curves at various rotational speeds. The portion of the curves in the limiting current regime where the current is independent of the potential, may be used to determine the diffusivity or concentration of a diffusing ion in the electrolyte. The current-potential curves below the limiting current potentials are used for evaluating kinetic information of the electrode reaction. 

The RHSE has the same limitation as the rotating disk that it cannot be used to study very fast electrochemical reactions. Since the evaluation of kinetic data with a RHSE requires a potential sweep to gradually change the reaction rate from the state of charge-transfer control to the state of mass transport control, the reaction rate constant thus determined can never exceed the rate of mass transfer to the electrode surface. An upper limit can be estimated by using Eq. (44). If one uses a typical Schmidt number of Sc 1000, a diffusivity D 10 5 cm/s, a nominal hemisphere radius a 0.3 cm, and a practically achievable rotational speed of 10000 rpm (Re 104), the mass transfer coefficient in laminar flow may be estimated to be ... 

Example 5-2 Kinetic Energy Correction Factor for Laminar Flow of a Newtonian Fluid. We will show later that the velocity profile for the laminar flow of a Newtonian fluid in fully developed flow in a circular tube is parabolic. Because the velocity is zero at the wall of the tube and maximum in the center, the equation for the profile is... 

Evaluate the kinetic energy correction factor a in Bernoulli s equation for turbulent flow assuming that the 1/7 power law velocity profile [Eq. (6-36)] is valid. Repeat this for laminar flow of a Newtonian fluid in a tube, for which the velocity profile is parabolic. 

The a s are the kinetic energy correction factors at the upstream and downstream points (recall that a = 2 for laminar flow and a = 1 for turbulent flow for a Newtonian fluid). 

A laminar-flow reactor (LFR) is rarely used for kinetic studies, since it involves a flow pattern that is relatively difficult to attain experimentally. However, the model based on laminar flow, a type of tubular flow, may be useful in certain situations, both in the laboratory and on a large scale, in which flow approaches this extreme (at low Re). Such a situation would involve low fluid flow rate, small tube size, and high fluid viscosity, either separately or in combination, as, for example, in the extrusion of high-molecular-weight polymers. Nevertheless, we consider the general features of an LFR at this stage for comparison with features of the other models introduced above. We defer more detailed discussion, including applications of the material balance, to Chapter 16. 

Ideal flow is introduced in Chapter 2 in connection with the investigation of kinetics in certain types of ideal reactor models, and in Chapter 11 in connection with chemical reactors as a contrast to nonideal flow. As its name implies, ideal flow is a model of flow which, in one of its various forms, may be closely approached, but is not actually achieved. In Chapter 2, three forms are described backmix flow (BMF), plug flow (PF), and laminar flow (LF). 

In the case of laminar flow in a pipe, work is done by the shear stress component rTX and the rate of doing work is the viscous dissipation rate, that is the conversion of kinetic energy into internal energy. The rate of viscous dissipation per unit volume at a point, is given by... 

Equation 2.37 is valid for any symmetric velocity profile. In the case of laminar flow of a Newtonian fluid, the velocity profile is given by equation 1.67, so the kinetic energy flow rate is found as... 

Thus the kinetic energy per unit mass of a Newtonian fluid in steady laminar flow through a pipe of circular cross section is u2. In terms of head this is u2/g. Therefore for laminar flow, a = i in equation 1.14. 

The average kinetic energy per unit mass can also be found as for laminar flow. The kinetic energy flow rate is given by... 

Yuasa H, Miyamoto Y, Iga T, Hanano M (1986) Determination of kinetic parameters of a carrier-mediated transport in the perfused intestine by two-dimensional laminar flow model Effects of the unstirred water layer. Biochim Biophys Acta 856 219-230... 

When the objective of the modeling effort is to develop and validate a reaction mechanism, the major uncertainty in the model must reside in the detailed chemical kinetic mechanism. Under these conditions, the process must be studied either under transport-free conditions, e.g., in plug-flow or stirred-tank reactors, or under conditions in which the transport phenomena can be modeled very precisely, e.g., under laminar flow conditions. This way. 

Figure 8-6 Plots of the ratio of conversions in a tubular reactor with laminar flow to that in a perfect PFTR for first- md second-order kinetics. The lower pmd shows the percent loss in conversion from l nin flow comp ed to plug flow.

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