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Lactones iterative tandem catalysis

Pahnans et al. prepared 5 by the reaction of [RuCl2(p-cymene)]2 and 2-phenyl-2-aminopropionamide in the presence of potassium carbonate. They used 5 in an iterative tandem catalysis for the synthesis of chiral oligoesters. The enzymatic ring opening of 6-methyl-e-caprolactone was combined with ruthenium-catalyzed alcohol racemization to produce optically active oligomers of 6-methyl-e-capro-lactone [23] (Scheme 1.17). [Pg.12]

Scheme 12 Chiral polymers from racemic co-methylated lactones by iterative tandem catalysis [105, 106]... Scheme 12 Chiral polymers from racemic co-methylated lactones by iterative tandem catalysis [105, 106]...
Iterative Tandem Catalysis Chiral Polymers from Racemic -Methylated Lactones... [Pg.294]

Ring-Opening of co-Substituted Lactones by Novozym 435 Selectivity Issues and Application to Iterative Tandem Catalysis... [Pg.230]

See other pages where Lactones iterative tandem catalysis is mentioned: [Pg.294]    [Pg.230]    [Pg.237]    [Pg.242]    [Pg.87]   
See also in sourсe #XX -- [ Pg.294 , Pg.295 ]



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