L-Octyl-3-methylimidazolium chloride

Arce, A., Rodriguez, O., and Soto A., Experimental determination of liquid-liquid equilibrium using ionic liquids tert-amyl ethyl ether + ethanol + l-octyl-3-methylimidazolium chloride system at 298.15 K, f. Chem. Eng. Data, 49, 514, 2004. 

Subsequently, H. Li et al. reported the s)Tithesis of plasmonic photocatalyst Ag/AgCl by an in situ hydrothermal method in the l-octyl-3-methylimidazolium chloride ([OmimJCl) ionic liquid, which served as not only a precursor but also a reducing reagent for the formation of Ag° nanoparticles. The chemical reactions could be described as following ... 

F) Water/l-octyl-3-methylimidazolium chloride (amphiphihc)/l-butyl-3-methyhmidazolium hexafluorophosphate (nonpolar phase) ... 

An IL-in-oil microemulsion [98] can be formulated by using an l-octyl-3-methylimidazolium chloride, [Cgmim][Cl], as IL-S and [C mim][PFJ as a substitute for traditional organic solvent. DLS was used to confirm the formation of [C mim] [PFJ-in-water microemulsions with an average size of 3 nm. 

Chen L, Zhou T, Chen L, et al. Selective oxidation of cyclohexanol to cyclohexanone in the ionic liquid l-octyl-3-methylimidazolium chloride. Chem Commun. 2011 47 9354-9356. 

Calvar, N. Gomez, E. Gonzalez, B. Dominguez, A. (2007). Experimental Determination, Correlation, and Prediction of Physical Properties of the Ternary Mixtures Ethanol + Water with l-Octyl-3-methylimidazolium Chloride and l-Ethyl-3-... 

Danielsson et al. [25] have studied the synthesis of PEDOT in ionic liquids that utilize bulky organic anions, l-butyl-3-methylimidazolium diethylene glycol monomethyl ether sulfate and l-butyl-3-methylimidazolium octyl sulfate, the latter of which is a solid at room temperature and thus requires the addition of either monomer or solvent (in this case water) to form a liquid at room temperature. Polymerization in a water-free ionic liquid was only possible in the octyl sulfate species, but the polymerization of EDOT was successful in aqueous solutions of both the ionic liquids (0.1 M). The ionic liquid anions appear to be mobile within the polymer, exchangeable with chloride ions at a polymer/KCl(aq) interface, but it is interesting that when the PEDOT is in aqueous solutions of the ionic liquid, at higher concentrations (0.01-0.1 M) the imidazolium cation can suppress this anion response. The ion mobility in both the ionic liquid and in the polymer film in contact with the solution is significantly increased by addition of water. 

---