Kirkwood-Buff integral

Kirkwood-Buff integrals of aqueous acetone mixtures, J. Chem. Physics 123, 23503, 2005 Zhou, J., Tao, G., Liu, Q. et al., Equilibrium yields of mono- and di-lauroyl mannoses through lipase-catalyzed condensation in acetone in the presence of molecular sieves, Biotechnol. Lett. 28, 395M00, 2006. 

The Kirkwood-Buff integrals and their applications to binary and ternary solutions... 

Kirkwood-Buff integrals in aqueous alcohol systems comparison between thermodynamic calculations and X - ray scattering experiments. 

Kirkwood—Buff Integrals in Aqueous Alcohol Systems Comparison between Thermodynamic Calculations and X-Ray Scattering Experiments... 

Many models are available for describing the thermodynamic behavior of solutions. " However, so far no one could satisfactorily simulate the solution behavior over the whole concentration range and provide the correct pressure and temperature dependencies. This generated interest in the thermodynamically rigorous theories of Kirkwood—Buff and McMillan—Mayer. In the present paper, the emphasis is on the application of the Kirkwood—Buff theory to the aqueous solutions of alcohols, because it is the only one which can describe the thermodynamic properties of a solution over the entire concentration range. The key quantities in the Kirkwood-Buff theory of solution are the so-called Kirkwood-Buff integrals (KBIs) defined as... 

TABLE 3 The Sources for the Kirkwood—Buff Integrals from SAXS Measurements... 

The aqueous systems of methanol, ethanol, propanols, and butanols were examined in the framework of the Kirkwood-Buff theory of solution. The Kirkwood—Buff integrals were calculated using thermodynamic equations, in which the derivatives (9 nyi/dxi)pj were expressed in terms of (9 nP/dXi)r, which... 

Kirkwood—Buff Integrals in Alcohol Systems According to eq 4... 

Kirkwood—Buff Integrals in Aqueous Alcohol Systems TABLE 1 Clustering in Aqueous Solutions of Alcohols J. Phys. Chem. B, Vol. 103, No. 5, 1999 873... 

Kirkwood—Buff Integrals in Aqueous Alcohol Systems... 

The Kirkwood—Buff Integrals. The Kirkwood—Buff integrals (KBI) are defined as ... 

TABLE 1 Sources of Data Used for Calculating the Kirkwood—Buff Integrals"... 

The Kirkwood—Buff theory of solutions was applied to the systems aromatic fluorocarbon/aromatic hydrocarbon. The Kirkwood-Buff integrals and the excess (or deficit) number of molecules around a central one were calculated for five systems (hexafluorobenzene—benzene, hexafluorobenzene—toluene, hexafluorobenzene—cyclohexane, benzene—toluene, benzene-cyclohexane). 

Keywords Fluctuation theory Kirkwood-Buff integrals A/,A -dimethylformamide Methanol Water Binary mixtures Ternary mixtures... 

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