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Kinetics of Ring-Opening Polymerization

There is general similarity between the kinetics of many ring-opening polymerizations and those of step-growth polymerizations that are discussed in Chapter 6. Some kinetic expressions in ring-opening polymerizations, on the other hand, resemble chain-growth ionic ones. [Pg.167]

When there is no termination in the ring-opening polymerizations and they behave like living polymerizations, the rate of propagation can be described similarly by [Pg.167]

The rate expression can then be written as the rate of propagation-depropagation  [Pg.168]

At conditions of equilibrium, if we designate the monomer concentration as [M]c and the polymerization rate is zero, we can write [Pg.168]

Hirota and Fukuda described the quantitative dependence of the degree of polymerization on various reaction parameters for an equilibrium polymerization. The initiation can be described as [Pg.168]

Yu Y, Storti G, Morbidelli M. Kinetics of ring-opening polymerization of L,L-lactide. Industrial Eng Chem Res 2011 50(13) 7927—40. [Pg.177]

I 7 Thermodynamics and Kinetics of Ring-Opening Polymerization 1.2.2.2 Monomer-Polymer-Solvent Interactions... [Pg.12]

Thermodf nannies and Kinetics of Ring-Opening Polymerization... [Pg.50]

Matsumoto, M., Odachi, D, and Kondo, K. (1999) Kinetics of ring-opening polymerization of lactones by lipase. Biochemical Engineering Journal, 4, 73-6,... [Pg.305]

See other pages where Kinetics of Ring-Opening Polymerization is mentioned: [Pg.3]    [Pg.41]    [Pg.52]    [Pg.167]    [Pg.167]    [Pg.253]    [Pg.121]    [Pg.1]    [Pg.2]    [Pg.4]    [Pg.10]    [Pg.14]    [Pg.16]    [Pg.18]    [Pg.20]    [Pg.22]    [Pg.24]    [Pg.25]    [Pg.26]    [Pg.27]    [Pg.28]    [Pg.29]    [Pg.31]    [Pg.33]    [Pg.34]    [Pg.35]    [Pg.36]    [Pg.37]    [Pg.38]    [Pg.39]    [Pg.40]    [Pg.41]    [Pg.43]    [Pg.46]    [Pg.48]   
See also in sourсe #XX -- [ Pg.253 , Pg.254 ]



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