Kinetic phase diagram

Figure 6-15. The kinetic phase diagram of high-vacuum-sublimcd T6 films as a function of deposition T and nominal substrate thickness h.

Chvoj, Z., Sestak, J. andTriska, A. (ed.) (1991) Kinetic Phase Diagrams. Non Equilibrium Phase Transitions (Elsevier Science, Amsterdam). 

Glass transition determinations Decomposition reaction Reaction kinetics Phase diagrams Dehydration reactions Solid-state reactions Heats of absorption Heats of reaction Heats of polymerization Heats of sublimation Heats of transition Catalysis... 

Figure 7.8. Three dimensional "kinetic" phase diagram for the influence of solution composition on the formation of dolomite. (After Morrow, 1982a.)...

This type of reaction represents the ultimate control solid-state synthetic chemists seek, namely, the bottom-up abUity to build a compound atom by atom. Harris et al. (2003) took advantage of the two dimensional nature of Bi2Te3 and TiTe2, such that their S5mthetic challenge was layer by layer. The secret to their success lies in the fact that two important principles control any synthetic efforts thermodynamics and kinetics. Phase diagrams, which are discussed in Chapter 11, owe allegiance to thermodynamics... 

Nis] Nishikawa, K., Kusano, A., Ito, K., Sano, K., The Effect of Alloying Elements on flie Solubility of Oxygen in 6-Iron , Tram. Iron Steel Imt. Jpn., 10, 83-88 (1970) (Experimental, Kinetics, Phase Diagram, Phase Relations, 17)... 

Aal] Aalders, L, Van Dijk, C., Radelaar, S., Neutron Scattering Study on Decomposition in Cop-per-Nickel-Iron Alloys , PAys. Rev. B, Cond. Matter, 30(4), 1646-1655 (1984) (Crys. Structure, Experimental, Kinetics, Phase Diagram, Phase Relations, Theory, 26)... 

Z. Chvoj, J. Sestak, A. Triska Kinetic Phase Diagrams (Elsevier, Amsterdam, 1984). 

Fig. 11.4 Comparison in the theoretical phase diagrams of phase separation and polymer crystallization in polymer solutions, and the kinetic phase diagrams of crystal nucleation. The energy parameters are set as EpIEc =1.0 and BlEc = 0.076 for the labeled Cl curves, EpjE = 1.072 and BjEc = 0.03 for C2, and EpjEc = 1.275 and BjEc = —0.1 for C3. Three solution series share the same melting points (solid lines) at polymer concentration ( = 0.125, but different depths of critical points for phase separation. The dashed lines are binodals, and the dotted lines are spinodals. The data points are the onset temperatures for the uprising of crystallite numbers on isothermal crystallization. The straight lines are drawn to guide the eyes (Zha and Hu2007) (Reprinted with permission)...

Fro] Fromm, E., Hoerz, G., Hydrogen, Nitrogen, Oxygen, and Carbon in Metals , Int. Mater. Rev., (5/6), 269-312 (1989) (Kinetics, Phase Diagram, Review, Thermodyn., 255)... 

Eno] Enomoto, M., Maruyama, N., Wu, K.M., Tarui, T., Alloying Element Accumulation at Ferrite/Austenite Boundaries Below the Time-Temperature-Transformation Diagram Bay in an Fe-C-Mo Alloy , Mater. Sci. Eng. A, 343, 151-157 (2003) (Calculation, Experimental, Kinetics, Phase Diagram, Phase Relations, 27)... 

Proks Evaluation of the Knowledge of Phase Equilibria first chapter in the book Kinetic Phase Diagrams (Z. Chvoj, J. Sestak, A. Tn ska, edts.), Elsevier, Amsterdam 1991... 

Fig. 4. Kinetic phase diagrams of [DEME][BF4]-H20 mixtures on (a) cooling and (b) heating. Closed circles represent observed data, which are determined by simultaneous WAXS-DSC measurements. Xcc and X are defined to be a critical concentration of the cold aystallization and the formation of H2O ice crystal, respectively. Tcc is the cold aystallization temp>erature with an exothermal peak on heating. Tmi and Tml are the melting temperatures, respectively. L, C, A, I and U represent the liquid, [DEME][BF4] crystal, amorphous, H2O ice and imdefined phases. U is classified further into (1+A)-, (I+C)-and (I+A+C)-phases.

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