Kalihinane diterpenoids

Fig. (4) Representative kalihinane diterpenoids isolated from the marine sponge Acanthella sp.

A similar catalytic aziridination has also been applied for the functionalization of the optically active azoninones 652 [772], in the preparation of a key intermediate 653 in the total synthesis of kalihinane diterpenoids [773], in the synthesis of a-methylserinal derivatives 654 (Scheme 3.259) [774], in the preparation of 2,4-disubstituted A-tosylpyrrolidines [775] and in the synthesis of nosylaziridines [776]. 

White, R.D. and Wood, J.L (2001) Progress toward the total synthesis of kalihinane diterpenoids. Org. Lett., 3,1825-1827. 

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