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Joullie

Broncloclar (Oberlin) Rhinathiol (Joullie) Solucis (Magis)... [Pg.346]

The facile arylation of aldehydes with arylboronic acid has prompted the exploration of asymmetric versions of this reaction. However, this field has been scarcely explored and only few examples have been reported in the literature, with moderate results. The first diastereoselective example was described by Ftirstner and coworkers. By reacting the Gamer aldehyde 15 with phenylboronic acid under their set of experimental conditions (i.e. RhClj-SH O, IPr HCl) (Scheme 7.4) [21], the secondary alcohol was obtained in higher selectivity than that observed in the addition of phenylmagnesium bromide reported by Joullie (de = 94% versus 66%), with the anti isomer as the major compound [29]. [Pg.196]

Diels-Alder cycloaddition of 5-bromo-2-pyrone with the electron-rich tert-butyldi-methylsilyl (TBS) enol ether of acetaldehyde, using superheated dichloromethane as solvent, has been investigated by Joullie and coworkers (Scheme 6.90) [188]. While the reaction in a sealed tube at 95 °C required 5 days to reach completion, the anticipated oxabicyclo[2.2.2]octenone core was obtained within 6 h by microwave irradiation at 100 °C. The endo adduct was obtained as the main product. Similar results and selectivities were also obtained with a more elaborate bis-olefin, although the desired product was obtained in diminished yield. Related cydoaddition reactions involving 2-pyrones have been discussed in Section 2.5.3 (see Scheme 2.4) [189]. [Pg.170]


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See also in sourсe #XX -- [ Pg.137 , Pg.203 , Pg.257 , Pg.405 , Pg.463 ]




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