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Isotope-induced chemical shift changes

Isotopic labels (and especially enriched materials) have proven crucial in the investigation of the mechanisms of homogeneously catalyzed reactions [130]. Further, isotope effects on the rate or the equilibrium constant of a reaction can be diagnostic, and structural information can be provided by isotope-induced changes in the chemical shifts of neighbouring nuclei, and/or alterations in the coupling pattern of the detected spectra. The isotope- and position-specific information inherent to NMR techniques are ideally suited for the analysis of isotope effects in catalysis [131]. [Pg.27]

See other pages where Isotope-induced chemical shift changes is mentioned: [Pg.599]    [Pg.87]    [Pg.18]    [Pg.85]    [Pg.339]    [Pg.250]    [Pg.481]    [Pg.3310]    [Pg.35]    [Pg.152]    [Pg.1276]    [Pg.14]    [Pg.14]    [Pg.227]    [Pg.14]    [Pg.60]    [Pg.300]    [Pg.207]    [Pg.85]    [Pg.102]    [Pg.80]    [Pg.111]    [Pg.138]    [Pg.85]    [Pg.201]    [Pg.125]   
See also in sourсe #XX -- [ Pg.250 ]



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