Isothiocyanate pentafluoride

V. Sulfur Isocyanate Pentafluoride and Sulfur Isothiocyanate Pentafluoride... [Pg.125]

The fluorination of alkyl and aryl isothiocyanates with iodine pentafluoride in pyridine solution affords bis[alkyl(or aryl)trifluoromethylamino] sulfides.137 Aromatic isothioeyanates react in a few minutes at 75-90 C. more readily than their alkyl counterparts. [Pg.258]

Iodine pentafluoride pyridine Thiobis-N-(trifluoromethyl)amines from isothiocyanates... [Pg.179]

A mixture of p-chlorophenyl isothiocyanate and pyridine warmed to 65°, then iodine pentafluoride added dropwise at such a rate as to maintain a temp, of 75-80°, finally stirred 10 min. at 80° thiobis-N-(p-chlorophenyl)-N-(trifluoro-methyl)amine. Y 94-95%. F. e. s. T. E. Stevens, J. Org. Ghem. 26, 3451 (1961). [Pg.130]

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