Isonicotinium dichromate oxidation

Oxidation of several primary aliphatic alcohols with potassium dichromate, pyri-dinium dichromate, quinolinium dichromate (QDC), imidazolium dichromate, nico-tinium dichromate, isonicotinium dichromate, pyridinium fluorochromate (PFC), quinolinium fluorochromate, imidazolium fluorochromate, pyridinium chlorochromate (PCC), quinolinium chlorochromate (QCC), and pyridinium bromochromate (PBC), in aqueous acetic acid and in the presence of perchloric acid, showed similar kinetics. The values of the reaction constants did not differ significantly, indicating operation of a common mechanism.1... [Pg.85]

Carboxypyridinium dichromate (isonicotinium dichromate) has also been prepared by Palomo and coworkers. It appears to have very similar properties to nicotinium dichromate, and offers no further advantage for the oxidation of alcohols. [Pg.277]