Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Isolated falling sphere

A number of situations may be visualized. Electron transfer may take place between a pair of redox proteins in solution. Certain reactions in the cytoplasm of the red blood cell fall into this category, such as that between hemoglobin and cytochrome b reductase. These reactions will probably occur by an outer-sphere mechanism, as was described earlier for model reactions between isolated electron-transfer proteins and also between these proteins and simple complexes. Interaction between such proteins probably utilizes specific charged areas on their surfaces. The possibility of inner-sphere reactions may have to be considered in a few cases. [Pg.712]

Its exponential behavior makes this term the dominant one when short atom-atom distances between the interacting molecules are produced. Consequently, this term prevents molecules from getting closer than some limiting distance this is the physical principle behind the hard-sphere model and Kitaigorodsky s close-packing principles [2]. Moreover, the shortest atom-atom distances that one can find in different intermolecular interactions for the same pair of atoms always fall in a restricted range, a fact that allows one to define atomic radii. They differ in ionic and neutral crystals due to the different electronic structure of ionic and neutral species, as easily shown when comparing the contours at 90% probability in electron density maps for isolated atoms and their ions. [Pg.37]


See other pages where Isolated falling sphere is mentioned: [Pg.30]    [Pg.30]    [Pg.240]    [Pg.96]    [Pg.240]    [Pg.46]    [Pg.102]    [Pg.117]    [Pg.199]    [Pg.212]    [Pg.223]    [Pg.331]    [Pg.101]    [Pg.214]    [Pg.1074]    [Pg.533]    [Pg.340]   
See also in sourсe #XX -- [ Pg.30 ]




SEARCH



Falling

Falls

Falls/falling

© 2024 chempedia.info