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Isoamyl alcohol decomposition

The deamination of phosphoramidates by isoamyl nitrite has been mentioned in previous Reports and is the basis of a method for the protection of 5 -phosphoryl groups in the synthesis of oligonucleotides. The oxidation of nucleoside phosphoramidates with bromine in the presence of alcohols leads to phosphodiesters. The AT-bromophosphoramidate which is presumably an intermediate should break down by a pathway which is similar to that of the acid-catalysed decomposition of phosphoramidates. [Pg.145]

See other pages where Isoamyl alcohol decomposition is mentioned: [Pg.29]    [Pg.694]    [Pg.401]    [Pg.319]    [Pg.85]    [Pg.706]    [Pg.44]    [Pg.69]    [Pg.590]    [Pg.147]    [Pg.286]   
See also in sourсe #XX -- [ Pg.64 ]



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Isoamyl

Isoamyl alcohol

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