Iridium dihydrate

Although Werner considered both enantiomers of potassium tris-(oxalato)chromate(III) to be monohydrates, Charonnat and Dele-pine, on the basis of isomorphism with the corresponding iridium salt, proposed that they are dihydrates. The (+) enantiomer has been described as bluish red in the dry, pure condition. - The optical enantiomers are less soluble in water than the racemic mixture. Because of the high rate of racemization in water, recrystallization has been reported to be accompanied by a considerable loss of optical rotation. For the same reason, the optical rotation values reported by different workers are not directly comparable. ... 

S.CrN.OinCMHij jHjO, Chromium(II), te-traaquabis( 1,2-benzisothiazol-3(2//)-one 1,1-dioxidato)-, dihydrate, 27 309 S2F6lr07P2C3,H3i, Iridium(III), carbonylhy-dridobis(trifluoromethanesulfonato)bis-(triphenylphosphine)-, 26 120 S2Mn20,P2C,2H,2, Manganese, octacar-bonyl-bis(p.-dimethylpho phinothioyl-P,S)di-, 26 162... 

CgflHg7BFftIr2P , Tris(M-hydrido)bis[hydrido(1,3-bis(diphenylphos-phino)propane)iridium] tetrafluoroborate, 46B, 1301 Cg4H9gAs2Co3N80ioP2 2 H2O, Bis((tri-n-butylphosphine)-bis(dimeth-ylglyoximato)-(methyl(phenyl)arsenyl)cobalt(III))-cobalt(II) dihydrate, 45B, 1380... 

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