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Iridium compounds IrH2

A related dehydrogenation of primary and secondary alcohols to the corresponding aldehydes/ketones has been achieved using the dihydride iridium compound [IrH2(C6H3-2,6 CH2P-t-Bu2 2)j as the precursor s catalyst and t-butylethylene as hydrogen acceptor (Eq. 13). The reactions are carried out at 200 °C with a 99% yield in 18 h (alcohol/Rh = 10/1) [55]. [Pg.226]

IrH2( /i/)2i 2]A systems, prepared in situ, are effective in the isomerization of allylic alcohols to carbonyl compounds, " and isomerization is always a side reaction in hydrogenation reactions with the iridium catalyst. [Pg.309]

See other pages where Iridium compounds IrH2 is mentioned: [Pg.34]    [Pg.56]    [Pg.331]    [Pg.334]    [Pg.244]    [Pg.244]    [Pg.366]    [Pg.260]    [Pg.276]    [Pg.244]    [Pg.244]    [Pg.1012]    [Pg.334]    [Pg.274]    [Pg.24]    [Pg.92]    [Pg.20]    [Pg.371]    [Pg.165]    [Pg.668]    [Pg.1189]    [Pg.9]    [Pg.244]    [Pg.389]    [Pg.277]    [Pg.311]   
See also in sourсe #XX -- [ Pg.2 , Pg.108 ]



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IRh2

Iridium compound

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