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IRh2

The complex [IrH2(Me2CO)(Hpz)(PPh3)2]BF4 is obtained as ttie result of a ready and selective substitution of acetone in [IrH2(Me2CO)2(PPh3)2]BF4 with... [Pg.180]

Ir(PMe2Ph)J + H2 -> IrH2(PMe2Ph)J With bulky phosphines, 6-coordinate structures are not possible [157]... [Pg.150]

Au(PPh3)((i-H)IrH2(PPh3)3,5, 869 Ir Au4C103H92P e [IrAu4H2(PPh3)6j+, 4, 1166 IrBC8H8N402... [Pg.400]

Treatment of mer-IrH3(PPh3)3 with N,N, N"-triphenylguanidine in refluxing toluene afforded the iridium(III) dihydride complex [PhNHC(NPh)2]IrH2... [Pg.287]

Oxidative addition of H2 and Ph3SiH to IrBr(CO)(chiraphos), where chiraphos 2,S, 3,S -bis (diphenylphosphino)butane, leads to stable kinetic (115a,115b), followed by thermodynamic (116a,116b) diastereomers as shown in reaction Scheme 15.2 3 The crystal structure of cis-[IrH2(chiraphos)2]BF4 has been reported.204... [Pg.173]

Theoretical studies of catalytic alkane-dehydrogenation reactions by [(PCP )IrH2], PCP rf-C6H3(CH2P112)2-l, 3 and [cpIr(PH3)(H)]+, suggest that they proceed through similar steps in both cases namely (i) alkane oxidation, (ii) dihydride reductive elimination, (iii) /3-II transfer from alkyl ligand to metal, (iv) elimination of olefin.402 The calculated barriers to steps (i), (ii), and (iv) are more balanced for the PCP system than for cp(PH3). [Pg.191]

See other pages where IRh2 is mentioned: [Pg.45]    [Pg.36]    [Pg.181]    [Pg.189]    [Pg.208]    [Pg.208]    [Pg.148]    [Pg.150]    [Pg.274]    [Pg.280]    [Pg.285]    [Pg.386]    [Pg.386]    [Pg.400]    [Pg.400]    [Pg.401]    [Pg.403]    [Pg.404]    [Pg.406]    [Pg.406]    [Pg.406]    [Pg.407]    [Pg.407]    [Pg.407]    [Pg.407]    [Pg.408]    [Pg.408]    [Pg.408]    [Pg.409]    [Pg.540]    [Pg.581]    [Pg.581]    [Pg.247]    [Pg.182]    [Pg.159]    [Pg.164]    [Pg.165]    [Pg.168]    [Pg.169]    [Pg.174]    [Pg.179]    [Pg.181]    [Pg.274]    [Pg.165]   
See also in sourсe #XX -- [ Pg.2 , Pg.6 , Pg.170 , Pg.207 ]

See also in sourсe #XX -- [ Pg.46 ]

See also in sourсe #XX -- [ Pg.46 ]



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Iridium compounds IrH2

Tp*IrH2

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