Iridium complexes isocyanides

C2H,N, Pyridine, 3,5-dimethyl-palladium complex, 26 210 CbHsNO, Benzoyl isocyanide chromium com-C HbO, Ethanone, 1-phenyl-manganese complex, 26 156-158 CBH, 02, Methyl benzoate chromium complex, 26 32 C H i, o-Xylylene magnesium complex, 26 147 ChH P, Phosphine, dimethylphenyl-iron complex, 26 61 ruthenium complex, 26 273 ChH12, 1,5-Cyclooctadiene iridium complex, 26 122 ruthenium complexes, 26 69-72, 253-256 ChH OjPS, 2-Butenedioic acid, 2-(dimethylphosphinothioyl)-dimethyl ester, manganese complex, 26 163... 

Bis[iV,iV -di(2-pyridyl)-imidazol-2-ylidene]aurate(I) tetrafluoroborates, preparation, 2, 292-293 Bis[iV,iV -di(2-pyridyl-methyl)-imidazol-2-ylidene]aurate(I) tetrafluoroborates, preparation, 2, 292-293 Bis(diselenolate) complexes, dinuclear iron compounds, 6, 242 Bis(dithiolene) compounds, in tungsten carbonyl and isocyanide complexes, 5, 644 Bis(enolato) complexes, with bis-Cp Ti(IV), 4, 589 Bis(enones), in reductive cyclizations, 10, 502 Bis(ethanethiolato) complexes, with bis-Cp Ti(IV), 4, 601 Bis(ethene)iridium complexes, preparation, 7, 328-329 -Bis(fluorenyl)zirconocene dichlorides, preparation,... 

Those iridium(III) isocyanide complexes obtained from oxidative addition to an iridium(I) isocyanide complex have been treated in Section 49.4.1.1. 

These iridium(I) isocyanide complexes show deep blue colors in solution due to the presence of oligomers [Ir(CNMe)4]S that are associated through intermetallic bonding. Photolysis of these oligomers results in their dissociation into monomers. Photolysis of a mixture of [Ir(CNMe)4]ir and MeNC leads to the... 

Lithium or potassium indenyl has been used to generate both iridium complexes and isocyanide rhodium complexes of the form (n indenyl)Rh(CNR)2. Bimetallic complexes of Co,Rh and Ir have been made using thallium fulvanate Tl2(CioH8)- With the linked permethylcyclopentadienyl lithium reagent dirhodium complexes such as (19) can be made. ... 

The most interesting work on the isocyanide complexes of the elements in this subgroup has been done with rhodium and iridium. For the most part, the work is involved with the oxidative addition reactions of d square-planar metal complexes. 

There are marked differences between the carbonyl cations of cobalt and its congeners, rhodium and iridium. For instance, the heavier elements form square-planar carbonyl cations as well as higher coordinate complexes. This is paralleled by the isocyanide cations thus cobalt forms [Co(CNR)5]+ cations (191), whereas rhodium and iridium form [M(CNR)4]+ cations (191, 192, 194). 

The square planar iridium isocyanide complexes [124] IrCl3... 

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