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2-Iodoxybenzenesulfonic acid

Zhdankin and co-workers reported <2004TL2719> the use of DMDO lb in the preparation of new pseudobenzio-doxole-based pentavalent iodine compounds 139, amides of 2-iodoxybenzenesulfonic acid, which are potentially useful reagents for mild oxidation of alcohols. [Pg.663]

Amides of 2-iodoxybenzenesulfonic acid 495 were prepared by dioxirane oxidation of the corresponding 2-iodobenzenesulfamides 494 and isolated as stable, microcrystalline products (Scheme 2.141) [660], A single-crystal X-ray structural analysis of the alanine derivative 495 [R = (5)-CH(CH3)C02Me] showed a combination of intra- and intermolecular I--0 interactions leading to a unique tieptacoordinated iodine(V) center in this molecule [661], The analogous esters 497 were prepared similarly from the respective sulfonate esters 496 [662],... [Pg.118]

A review focuses on the discovery and development of 2-iodoxybenzenesulfonic acid and related hypervalent iodine compounds that are chemoselective oxidants and environmentally benign. It covers advances in hypervalent iodine-catalysed alcohol oxidations and related transformations. ... [Pg.101]

See other pages where 2-Iodoxybenzenesulfonic acid is mentioned: [Pg.124]    [Pg.242]    [Pg.51]    [Pg.124]    [Pg.242]    [Pg.51]    [Pg.75]   
See also in sourсe #XX -- [ Pg.75 ]

See also in sourсe #XX -- [ Pg.101 ]

See also in sourсe #XX -- [ Pg.51 ]



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